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Wiley's J.D. Lee Concise Inorganic Chemistry for JEE (Main & Advanced) 2025 | By Sudarsan Guha | Fifth Edition | Wiley Publication ( English Medium )
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| 785-1019 |
Wiley's J.D. Lee Concise Inorganic Chemistry for JEE (Main & Advanced) 2025 | By Sudarsan Guha | Fifth Edition | Wiley Publication ( English Medium ).
The book is an adaptation of the classic book Concise Inorganic Chemistry by J.D. Lee (Fifth Edition), which is widely used by students preparing for JEE. This adapted version provides a more concise and relevant treatment of Inorganic Chemistry as per JEE syllabus requirements. The concepts are explained in a simple and straightforward manner. Yet the book provides a thorough grounding of the subject, helping students approach the examination with confidence.
About The Author:-
John Lee was a Senior Lecturer in the Department of Chemistry at Loughborough University, Leicestershire.
Table Of Contents:-
Preface
Note to the Student
1. Structure of an Atom
1.1 Atoms
1.2 Some Important Definitions
1.3 Electronic Configuration of an Atom
Quantum numbers
Aufbau principle
Pauli exclusion principle
Hund’s rule
Stability of half-filled and fully-filled shells
Electronic configuration of ions
Nodal planes of different orbitals
Slater’s rule
Single Correct Choice Type Questions
Multiple Correct Choice Type Questions
Comprehension Type Questions
Assertion-Reasoning Type Questions
Integer Answer Type Questions
Matrix-Match Type Questions
Answers
2. Periodic Table and Periodic Properties
2.1 Periodic Table
Genesis of periodic classification
Moseley’s work
Modern periodic law
2.2 Classification of Elements Based on Electronic Configuration
Prediction of period and group number of an element from its electronic configuration
Neil Bohr’s classification
Naming of super heavy elements
2.3 Periodic Trends in Properties
Atomic radius
Ionic radius
Ionization energy
Applications of ionization energy
Electron affinity
Electronegativity
Lattice energy
Hydration energy
Ionic mobility
Single Correct Choice Type Questions
Multiple Correct Choice Type Questions
Comprehension Type Questions
Assertion–Reasoning Type Questions
Integer Answer Type Questions
Matrix–Match Type Questions
Answers
3. Chemical Bonding
3.1 Attainment of a Stable Configuration
3.2 Types of Bonds
3.3 Transitions Between the Main Types of Bonding
Ionic bonds
Covalent bonds
Oxidation numbers
Coordinate bonds
Double and triple bonds
Metallic bonds and metallic structures
3.4 The Covalent Bond
The Lewis theory
Sidgwick–Powell theory
3.5 Valence Bond Theory
What is the essence of hybridization?
Features of hybrid orbitals
Calculation of steric number
3.6 Valence Shell Electron Pair Repulsion (VSEPR) Theory
Effect of lone pair
Effect of double bond
Effect of electronegativity
Back bonding
3.7 The Extent of d Orbital Participation in Molecular Bonding
3.8 Types of Covalent Bonds (Sigma (s ) and Pi (p ) Bonds)
Bridge bonding
3.9 Molecular Orbital Method
3.10 LCAO Method
s–s combinations of orbitals
s–p combinations of orbitals
p–p combinations of orbitals
p–d combinations of orbitals
d–d combinations of orbitals
Non-bonding combinations of orbitals
3.11 Rules for Linear Combination of Atomic Orbitals
3.12 Examples of Molecular Orbital Treatment for Homonuclear Diatomic Molecules
H2+ molecule ion
H2 molecule
He2+ molecule ion
He2 molecule
Li2 molecule
Be2 molecule
B2 molecule
C2 molecule
N2 molecule
O2 molecule
O-2 ion
F2 molecule
3.13 Examples of Molecular Orbital Treatment for Heteronuclear
Diatomic Molecules
NO molecule
CO molecule
3.14 Dipole Moment
Application of dipole moment
Some special cases
3.15 The Ionic Bond
Radius ratio rules
Calculation of some limiting radius ratio values
3.16 Close Packing
3.17 Ionic Compounds of the Type AX (ZnS, NaCl, CsCl)
Structures of zinc sulphide
Sodium chloride structure
Caesium chloride structure
3.18 Ionic Compounds of the Type AX2 (CaF2, TiO2, SiO2)
Calcium fluoride (fluorite) structure
Rutile structure
b-cristobalite (silica) structure
3.19 Layer Structures (CdI2, CdCl2, [NiAs])
Cadmium iodide structure
Cadmium chloride structure
Nickel arsenide structure
3.20 Lattice Energy
3.21 Stoichiometric Defects
Schottky defects
Frenkel defects
3.22 Nonstoichiometric Defects
Metal excess
Metal deficiency
3.23 Born–Haber Cycle
3.24 Polarizing Power and Polarizability – Fajans’ Rules
Properties of ionic compounds affected by polarization
3.25 Melting Point of Ionic Compounds
3.26 Solubility of Ionic Compounds
Prediction of solubility order in ionic compounds
3.27 Electrical Conductivity and Colour
3.28 Acidic Nature of Oxides
3.29 Thermal Stability of Ionic Compounds
3.30 Weak Forces
Attractive intermolecular forces
Repulsive intermolecular forces
Lennard–Jones potential
3.31 Interactions between Ions and Covalent Molecules
3.32 The Metallic Bond
Conductivity
Lustre
Malleability and cohesive force
Crystal structures of metals
Bond lengths
3.33 Theories of Bonding in Metals
Free electron theory
Valence bond theory
Molecular orbital or band theory
3.34 Conductors, Insulators and Semiconductors
Single Correct Choice Type Questions
Multiple Correct Choice Type Questions
Comprehension Type Questions
Assertion–Reasoning Type Questions
Integer Answer Type Questions
Matrix–Match Type Questions
Answers
4. Hydrolysis
4.1 Introduction
4.2 Hydrolysis Through SN1 Mechanism
4.3 Hydrolysis Through SN2 Mechanism
4.4 Hydrolysis Through Addition–Elimination Mechanism
4.5 Hydrolysis Through Addition Mechanism
4.6 Hydrolysis Through Redox Reaction
4.7 Hydrolysis Through Push–Pull Mechanism
4.8 Hydrolysis Through Mixed Mechanism
Single Correct Choice Type Questions
Multiple Correct Choice Type Questions
Comprehension Type Questions
Assertion–Reasoning Type Questions
Integer Answer Type Questions
Matrix–Match Type Questions
Answers
5. Coordination Compounds
5.1 Double Salts and Coordination Compounds
5.2 Werner’s Work
5.3 More Recent Methods of Studying Complexes
5.4 Classification of Ligands
5.5 Effective Atomic Number (EAN)
Sidgwick EAN rule
5.6 Shapes of d Orbitals
5.7 Bonding in Transition Metal Complexes
Valence bond theory
Crystal field theory
Molecular orbital theory
5.8 Valence Bond Theory
5.9 Crystal Field Theory
Octahedral complexes
5.10 Effects of Crystal Field Splitting
5.11 Tetragonal Distortion of Octahedral Complexes (Jahn-Teller Distortion)
5.12 Square Planar Arrangements
5.13 Tetrahedral Complexes
5.14 Magnetism
5.15 Extension of the Crystal Field Theory to Allow for Some Covalency
5.16 Nomenclature of Coordination Compounds
5.17 Isomerism
Polymerization isomerism
Ionization isomerism
Hydrate isomerism
Linkage isomerism
Coordination isomerism
Coordination position isomerism
Geometrical isomerism and optical isomerism
Single Correct Choice Type Questions
Multiple Correct Choice Type Questions
Comprehension Type Questions
Assertion–Reasoning Type Questions
Integer Answer Type Questions
Matrix–Match Type Questions
Answers
vii
6. Metallurgy
6.1 Types of Ores
6.2 Principal Steps in the Recovery of a Metal from its Ore
6.3 Concentration or Dressing of Ore
Gravity separation or levigation
Magnetic separation
Froth floatation or oil floatation
Chemical method of separation: leaching
6.4 Conversion of Concentrated Ore into its Oxide
Calcination
Roasting
6.5 Different Reduction Processes
Carbon reduction
Self reduction
Thermite reduction (or Goldschmidt-Thermite process)
Metal replacement method (Hydrometallurgy)
Electrolytic reduction
Thermal decomposition method
6.6 Purification or Refining of Metal
Thermal refining
Electrorefining
6.7 Thermodynamics of Reduction Process
6.8 Alloys and Amalgams
Classification of alloys
Characteristics of alloys
Preparation of alloys
Amalgam
6.9 Different Types of Furnaces Used in Metallurgy
6.10 Extraction of Silver
Refining of Ag
6.11 Extraction of Gold by Cyanide Process
Refining of Au
6.12 Extraction of Tin
Refining of Sn
6.13 Extraction of Magnesium
Electrolytic reduction
Carbon reduction process
Other processes
6.14 Extraction of Aluminium
Beneficiation of bauxite
Electrolytic reduction of pure Al
Electrorefining of aluminium
6.15 Extraction of Lead
Carbon reduction
Self reduction process
Refining of lead
6.16 Extraction of Copper
Refining of blister copper
6.17 Extraction of Zinc
6.18 Extraction of Iron
Purification of iron or preparation of wrought iron
Steel making
Single Correct Choice Type Questions
Multiple Correct Choice Type Questions
Comprehension Type Questions
Assertion–Reasoning Type Questions
Integer Answer Type Questions
Matrix–Match Type Questions
Answers
7. Qualitative Salt Analysis
Tests for Acid Radicals
7.1 Action of Dilute Acids
7.2 Tests for CO2
3
-/HCO-
3 and SO2
3
-/HSO-
3 Radicals
Distinction between carbonate and bicarbonate
Detection of carbonate and bicarbonate when both are present together
Distinction between sulphite and bisulphite
Some other tests for SO2
3
- ions
7.3 Tests for Sulphide (S2-) Radical
7.4 Tests for Thiosulphate (S2O3
2-) Radical
7.5 Tests for Nitrite (NO2
-) Radical
7.6 Tests for Acetate, Formate and Oxalate Radicals
Specific test for acetate (cacodyl oxide test)
Specific test for formate (mercury (II) formate test)
Specific tests for oxalate
7.7 Tests for Halide (Cl-, Br-, I-) Radicals
Specific test for Cl - (chromyl chloride test)
Specific test for Br- and I - (layer test)
Other test for Br−
Other tests for I −
7.8 Tests for Nitrate (NO3
-) Radical
7.9 Tests for Sulphate (SO2
4
-) Radical
7.10 Tests for Borate (BO3
3
-) Radical 286
7.11 Tests for Phosphate (PO3
4
-) Radical 287
7.12 Tests for Chromate (CrO2
4
-) and Dichromate (Cr2O2
7
-) Radicals
7.13 Tests for Permanganate (MnO-
4) and Manganate (MnO2
4
-) Radicals
Tests for Basic Radicals
7.14 Dry Tests for Basic Radicals
Heating effects on the dry sample
Flame test
Borax bead test
Sodium carbonate bead test
7.15 Wet Tests for Basic Radicals
Classification of cations (group analysis)
7.16 Some General Tests for Cations
Tests for group V cations
Tests for group VI and zero group cations
7.17 Specific Tests for Some Cations
Heating Effects
Single Correct Choice Type Questions
Multiple Correct Choice Type Questions
Comprehension Type Questions
Assertion–Reasoning Type Questions
Integer Answer Type Questions
Matrix–Match Type Questions
Answers
8. Hydrogen and the Hydrides
8.1 Electronic Structure
8.2 Position in the Periodic Table
8.3 Abundance of Hydrogen
8.4 Preparation of Hydrogen
8.5 Properties of Molecular Hydrogen
Physical properties
Chemical properties
Use of hydrogen as fuel
8.6 Isotopes of Hydrogen
8.7 Ortho and Para Hydrogen
8.8 Hydrides
Ionic or salt-like hydrides
Covalent hydrides
Metallic (or interstitial) hydrides
Intermediate hydrides
8.9 The Hydrogen Ion
8.10 Hydrogen Bonding
Intermolecular hydrogen bonding
Intramolecular hydrogen bonding
Strength of hydrogen bonding
Extent of hydrogen bonding
Special cases of hydrogen bonding
Single Correct Choice Type Questions
Multiple Correct Choice Type Questions
Comprehension Type Questions
Assertion–Reasoning Type Questions
Integer Answer Type Questions
Matrix–Match Type Questions
Answers
9. The s-Block Elements and their Compounds Group 1 – The Alkali Metals
9.1 General Properties
Electronic structure
Size of atoms and ions
Density
Ionization energy
Electronegativity and bond type
9.2 Structures of the Metals, Hardness and Cohesive Energy
Melting and boiling points
9.3 Flame Colours and Spectra
9.4 Colour of Compounds
9.5 Chemical Properties
Reaction with water
Reaction with air
Reaction with dinitrogen
9.6 Oxides, Hydroxides, Peroxides and Superoxides
Reaction with air
Normal oxides – monoxides
Hydroxides
Peroxides and superoxides
9.7 Sulphides
9.8 Oxosalts – Carbonates, Bicarbonates, Nitrates, Nitrites and Sulphates
9.9 Halides and Polyhalides
9.10 Hydrides
9.11 Solubility and Hydration
9.12 Solutions of Metals in Liquid Ammonia
9.13 Compounds with Carbon
9.14 Complexes, Crowns and Crypts
9.15 Biological Importance
9.16 Differences between Lithium and the Other Group 1 Elements
9.17 Preparation of Sodium Hydroxide
9.18 Electrolytic Processes
Diaphragm cell
Mercury cathode cell
9.19 Preparation of Sodium Carbonate
9.20 The Solvay (or Ammonia – Soda) Process
Group 2 – The Alkaline Earth Elements
9.21 General Properties
Electronic structure
Size of atoms and ions
Ionization energy
Electronegativity
Hydration energies
Solubility and lattice energy
Solutions of the metals in liquid ammonia
9.22 Anomalous Behaviour of Beryllium
9.23 Chemical Properties
Reaction with water
9.24 Hydroxides
9.25 Hardness of Water
9.26 Reaction with Acids and Bases
9.27 Oxides and Peroxides
9.28 Sulphates
9.29 Nitrates
9.30 Hydrides
9.31 Halides
9.32 Nitrides
9.33 Carbides
9.34 Complexes
9.35 Biological Role of Mg2+ and Ca2+
9.36 Differences between Beryllium and the Other Group 2 Elements
Single Correct Choice Type Questions
Multiple Correct Choice Type Questions
Comprehension Type Questions
Assertion–Reasoning Type Questions
Integer Answer Type Questions
Matrix–Match Type Questions
Answers
10. The p-Block Elements and their Compounds
Part 1: The Group 13 Elements
10.1 Oxidation States and Types of Bonds
The (+III) oxidation state
The (+I) oxidation state – the ‘inert pair effect’
10.2 General Properties
Melting points, boiling points and structures i
Size of atoms and ions
Electropositive character
Ionization energy
10.3 Preparation of Boron
10.4 Reactions of Boron
10.5 Reactions of the Other Elements
Reaction with water and air
Reaction with acids and alkalis
Reaction with dioxygen
Reaction with the halogens and sulphate
Alums
Cement
10.6 Compounds of Boron and Oxygen
Boron sesquioxide and the borates
Acidic properties of H3BO3 or B(OH)3
Structures of borates
Borax
Sodium peroxoborate
Qualitative analysis of boron compounds
Fluoboric acid
10.7 The Other Group 13 Oxides
Preparation of Al2O3
Amphoteric behaviour – aluminates
10.8 Tetrahydridoborates (Borohydrides)
10.9 Halides
Trihalides
Dihalides
10.10 Complexes
10.11 Differences Between Boron and the Other Elements (Anomalous Behaviour of Boron)
10.12 Boron Hydrides
Compounds known
Preparation
10.13 Reactions of the Boranes
Hydroboration
Reaction with ammonia
Some other reactions of boranes
10.14 Structures of the Boranes
10.15 Organometallic Compounds
Single Correct Choice Type Questions
Multiple Correct Choice Type Questions
Comprehension Type Questions
Assertion–Reasoning Type Questions
Integer Answer Type Questions
Matrix–Match Type Questions
Answers
Part 2: The Group 14 Elements
10.16 Structure and Allotropy of the Elements
10.17 Differences Between Carbon, Silicon and the Remaining
Elements
10.18 Physical Properties
Covalent radii
Ionization energy
Melting points
Metallic and non-metallic character
Four-covalent compounds
10.19 Chemical Reactivity
Inert pair effect
10.20 Carbides
Salt-like carbides
Interstitial carbides
Covalent carbides
10.21 Oxygen Compounds of Carbon
Carbon monoxide CO
Carbon dioxide CO2
Carbon suboxides
10.22 Carbonates
10.23 Sulphides of Carbon
10.24 Oxides of Silicon
10.25 Oxides of Tin and Lead
Oxides of Tin
Oxides of Lead
10.26 Silicates
Occurrence in the Earth’s crust
Soluble silicates
10.27 Classification of Silicates
Orthosilicates (neso-silicates)
Pyrosilicates (soro-silicates, disilicates)
Cyclic silicates
Chain silicates
Sheet silicates (phyllo-silicates)
Three-dimensional silicates
10.28 Glass
10.29 Organosilicon Compounds and the Silicones
Organosilicon compounds
Preparation of organosilicon compounds
Silicones
10.30 Hydrides of Silicon
10.31 Complexes
10.32 Internal p Bonding Using d Orbitals
10.33 Halides
Tetrahalides
Catenated halides
Dihalides
10.34 Organic Derivatives
Single Correct Choice Type Questions
Multiple Correct Choice Type Questions
Comprehension Type Questions.
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| SKU, Publisher | Wiley-Con Inorg Chem-Guha(E) |
| Publisher | Wiley Publication |
| Author, Edition | By Sudarsan Guha, 5th Edition, English Medium |
| Binding, Type | Paperback, New |
| No. of Pages | 696 |
Wiley's J.D. Lee Concise Inorganic Chemistry for JEE (Main & Advanced) 2025 | By Sudarsan Guha | Fifth Edition | Wiley Publication ( English Medium ).
The book is an adaptation of the classic book Concise Inorganic Chemistry by J.D. Lee (Fifth Edition), which is widely used by students preparing for JEE. This adapted version provides a more concise and relevant treatment of Inorganic Chemistry as per JEE syllabus requirements. The concepts are explained in a simple and straightforward manner. Yet the book provides a thorough grounding of the subject, helping students approach the examination with confidence.
About The Author:-
John Lee was a Senior Lecturer in the Department of Chemistry at Loughborough University, Leicestershire.
Table Of Contents:-
Preface
Note to the Student
1. Structure of an Atom
1.1 Atoms
1.2 Some Important Definitions
1.3 Electronic Configuration of an Atom
Quantum numbers
Aufbau principle
Pauli exclusion principle
Hund’s rule
Stability of half-filled and fully-filled shells
Electronic configuration of ions
Nodal planes of different orbitals
Slater’s rule
Single Correct Choice Type Questions
Multiple Correct Choice Type Questions
Comprehension Type Questions
Assertion-Reasoning Type Questions
Integer Answer Type Questions
Matrix-Match Type Questions
Answers
2. Periodic Table and Periodic Properties
2.1 Periodic Table
Genesis of periodic classification
Moseley’s work
Modern periodic law
2.2 Classification of Elements Based on Electronic Configuration
Prediction of period and group number of an element from its electronic configuration
Neil Bohr’s classification
Naming of super heavy elements
2.3 Periodic Trends in Properties
Atomic radius
Ionic radius
Ionization energy
Applications of ionization energy
Electron affinity
Electronegativity
Lattice energy
Hydration energy
Ionic mobility
Single Correct Choice Type Questions
Multiple Correct Choice Type Questions
Comprehension Type Questions
Assertion–Reasoning Type Questions
Integer Answer Type Questions
Matrix–Match Type Questions
Answers
3. Chemical Bonding
3.1 Attainment of a Stable Configuration
3.2 Types of Bonds
3.3 Transitions Between the Main Types of Bonding
Ionic bonds
Covalent bonds
Oxidation numbers
Coordinate bonds
Double and triple bonds
Metallic bonds and metallic structures
3.4 The Covalent Bond
The Lewis theory
Sidgwick–Powell theory
3.5 Valence Bond Theory
What is the essence of hybridization?
Features of hybrid orbitals
Calculation of steric number
3.6 Valence Shell Electron Pair Repulsion (VSEPR) Theory
Effect of lone pair
Effect of double bond
Effect of electronegativity
Back bonding
3.7 The Extent of d Orbital Participation in Molecular Bonding
3.8 Types of Covalent Bonds (Sigma (s ) and Pi (p ) Bonds)
Bridge bonding
3.9 Molecular Orbital Method
3.10 LCAO Method
s–s combinations of orbitals
s–p combinations of orbitals
p–p combinations of orbitals
p–d combinations of orbitals
d–d combinations of orbitals
Non-bonding combinations of orbitals
3.11 Rules for Linear Combination of Atomic Orbitals
3.12 Examples of Molecular Orbital Treatment for Homonuclear Diatomic Molecules
H2+ molecule ion
H2 molecule
He2+ molecule ion
He2 molecule
Li2 molecule
Be2 molecule
B2 molecule
C2 molecule
N2 molecule
O2 molecule
O-2 ion
F2 molecule
3.13 Examples of Molecular Orbital Treatment for Heteronuclear
Diatomic Molecules
NO molecule
CO molecule
3.14 Dipole Moment
Application of dipole moment
Some special cases
3.15 The Ionic Bond
Radius ratio rules
Calculation of some limiting radius ratio values
3.16 Close Packing
3.17 Ionic Compounds of the Type AX (ZnS, NaCl, CsCl)
Structures of zinc sulphide
Sodium chloride structure
Caesium chloride structure
3.18 Ionic Compounds of the Type AX2 (CaF2, TiO2, SiO2)
Calcium fluoride (fluorite) structure
Rutile structure
b-cristobalite (silica) structure
3.19 Layer Structures (CdI2, CdCl2, [NiAs])
Cadmium iodide structure
Cadmium chloride structure
Nickel arsenide structure
3.20 Lattice Energy
3.21 Stoichiometric Defects
Schottky defects
Frenkel defects
3.22 Nonstoichiometric Defects
Metal excess
Metal deficiency
3.23 Born–Haber Cycle
3.24 Polarizing Power and Polarizability – Fajans’ Rules
Properties of ionic compounds affected by polarization
3.25 Melting Point of Ionic Compounds
3.26 Solubility of Ionic Compounds
Prediction of solubility order in ionic compounds
3.27 Electrical Conductivity and Colour
3.28 Acidic Nature of Oxides
3.29 Thermal Stability of Ionic Compounds
3.30 Weak Forces
Attractive intermolecular forces
Repulsive intermolecular forces
Lennard–Jones potential
3.31 Interactions between Ions and Covalent Molecules
3.32 The Metallic Bond
Conductivity
Lustre
Malleability and cohesive force
Crystal structures of metals
Bond lengths
3.33 Theories of Bonding in Metals
Free electron theory
Valence bond theory
Molecular orbital or band theory
3.34 Conductors, Insulators and Semiconductors
Single Correct Choice Type Questions
Multiple Correct Choice Type Questions
Comprehension Type Questions
Assertion–Reasoning Type Questions
Integer Answer Type Questions
Matrix–Match Type Questions
Answers
4. Hydrolysis
4.1 Introduction
4.2 Hydrolysis Through SN1 Mechanism
4.3 Hydrolysis Through SN2 Mechanism
4.4 Hydrolysis Through Addition–Elimination Mechanism
4.5 Hydrolysis Through Addition Mechanism
4.6 Hydrolysis Through Redox Reaction
4.7 Hydrolysis Through Push–Pull Mechanism
4.8 Hydrolysis Through Mixed Mechanism
Single Correct Choice Type Questions
Multiple Correct Choice Type Questions
Comprehension Type Questions
Assertion–Reasoning Type Questions
Integer Answer Type Questions
Matrix–Match Type Questions
Answers
5. Coordination Compounds
5.1 Double Salts and Coordination Compounds
5.2 Werner’s Work
5.3 More Recent Methods of Studying Complexes
5.4 Classification of Ligands
5.5 Effective Atomic Number (EAN)
Sidgwick EAN rule
5.6 Shapes of d Orbitals
5.7 Bonding in Transition Metal Complexes
Valence bond theory
Crystal field theory
Molecular orbital theory
5.8 Valence Bond Theory
5.9 Crystal Field Theory
Octahedral complexes
5.10 Effects of Crystal Field Splitting
5.11 Tetragonal Distortion of Octahedral Complexes (Jahn-Teller Distortion)
5.12 Square Planar Arrangements
5.13 Tetrahedral Complexes
5.14 Magnetism
5.15 Extension of the Crystal Field Theory to Allow for Some Covalency
5.16 Nomenclature of Coordination Compounds
5.17 Isomerism
Polymerization isomerism
Ionization isomerism
Hydrate isomerism
Linkage isomerism
Coordination isomerism
Coordination position isomerism
Geometrical isomerism and optical isomerism
Single Correct Choice Type Questions
Multiple Correct Choice Type Questions
Comprehension Type Questions
Assertion–Reasoning Type Questions
Integer Answer Type Questions
Matrix–Match Type Questions
Answers
vii
6. Metallurgy
6.1 Types of Ores
6.2 Principal Steps in the Recovery of a Metal from its Ore
6.3 Concentration or Dressing of Ore
Gravity separation or levigation
Magnetic separation
Froth floatation or oil floatation
Chemical method of separation: leaching
6.4 Conversion of Concentrated Ore into its Oxide
Calcination
Roasting
6.5 Different Reduction Processes
Carbon reduction
Self reduction
Thermite reduction (or Goldschmidt-Thermite process)
Metal replacement method (Hydrometallurgy)
Electrolytic reduction
Thermal decomposition method
6.6 Purification or Refining of Metal
Thermal refining
Electrorefining
6.7 Thermodynamics of Reduction Process
6.8 Alloys and Amalgams
Classification of alloys
Characteristics of alloys
Preparation of alloys
Amalgam
6.9 Different Types of Furnaces Used in Metallurgy
6.10 Extraction of Silver
Refining of Ag
6.11 Extraction of Gold by Cyanide Process
Refining of Au
6.12 Extraction of Tin
Refining of Sn
6.13 Extraction of Magnesium
Electrolytic reduction
Carbon reduction process
Other processes
6.14 Extraction of Aluminium
Beneficiation of bauxite
Electrolytic reduction of pure Al
Electrorefining of aluminium
6.15 Extraction of Lead
Carbon reduction
Self reduction process
Refining of lead
6.16 Extraction of Copper
Refining of blister copper
6.17 Extraction of Zinc
6.18 Extraction of Iron
Purification of iron or preparation of wrought iron
Steel making
Single Correct Choice Type Questions
Multiple Correct Choice Type Questions
Comprehension Type Questions
Assertion–Reasoning Type Questions
Integer Answer Type Questions
Matrix–Match Type Questions
Answers
7. Qualitative Salt Analysis
Tests for Acid Radicals
7.1 Action of Dilute Acids
7.2 Tests for CO2
3
-/HCO-
3 and SO2
3
-/HSO-
3 Radicals
Distinction between carbonate and bicarbonate
Detection of carbonate and bicarbonate when both are present together
Distinction between sulphite and bisulphite
Some other tests for SO2
3
- ions
7.3 Tests for Sulphide (S2-) Radical
7.4 Tests for Thiosulphate (S2O3
2-) Radical
7.5 Tests for Nitrite (NO2
-) Radical
7.6 Tests for Acetate, Formate and Oxalate Radicals
Specific test for acetate (cacodyl oxide test)
Specific test for formate (mercury (II) formate test)
Specific tests for oxalate
7.7 Tests for Halide (Cl-, Br-, I-) Radicals
Specific test for Cl - (chromyl chloride test)
Specific test for Br- and I - (layer test)
Other test for Br−
Other tests for I −
7.8 Tests for Nitrate (NO3
-) Radical
7.9 Tests for Sulphate (SO2
4
-) Radical
7.10 Tests for Borate (BO3
3
-) Radical 286
7.11 Tests for Phosphate (PO3
4
-) Radical 287
7.12 Tests for Chromate (CrO2
4
-) and Dichromate (Cr2O2
7
-) Radicals
7.13 Tests for Permanganate (MnO-
4) and Manganate (MnO2
4
-) Radicals
Tests for Basic Radicals
7.14 Dry Tests for Basic Radicals
Heating effects on the dry sample
Flame test
Borax bead test
Sodium carbonate bead test
7.15 Wet Tests for Basic Radicals
Classification of cations (group analysis)
7.16 Some General Tests for Cations
Tests for group V cations
Tests for group VI and zero group cations
7.17 Specific Tests for Some Cations
Heating Effects
Single Correct Choice Type Questions
Multiple Correct Choice Type Questions
Comprehension Type Questions
Assertion–Reasoning Type Questions
Integer Answer Type Questions
Matrix–Match Type Questions
Answers
8. Hydrogen and the Hydrides
8.1 Electronic Structure
8.2 Position in the Periodic Table
8.3 Abundance of Hydrogen
8.4 Preparation of Hydrogen
8.5 Properties of Molecular Hydrogen
Physical properties
Chemical properties
Use of hydrogen as fuel
8.6 Isotopes of Hydrogen
8.7 Ortho and Para Hydrogen
8.8 Hydrides
Ionic or salt-like hydrides
Covalent hydrides
Metallic (or interstitial) hydrides
Intermediate hydrides
8.9 The Hydrogen Ion
8.10 Hydrogen Bonding
Intermolecular hydrogen bonding
Intramolecular hydrogen bonding
Strength of hydrogen bonding
Extent of hydrogen bonding
Special cases of hydrogen bonding
Single Correct Choice Type Questions
Multiple Correct Choice Type Questions
Comprehension Type Questions
Assertion–Reasoning Type Questions
Integer Answer Type Questions
Matrix–Match Type Questions
Answers
9. The s-Block Elements and their Compounds Group 1 – The Alkali Metals
9.1 General Properties
Electronic structure
Size of atoms and ions
Density
Ionization energy
Electronegativity and bond type
9.2 Structures of the Metals, Hardness and Cohesive Energy
Melting and boiling points
9.3 Flame Colours and Spectra
9.4 Colour of Compounds
9.5 Chemical Properties
Reaction with water
Reaction with air
Reaction with dinitrogen
9.6 Oxides, Hydroxides, Peroxides and Superoxides
Reaction with air
Normal oxides – monoxides
Hydroxides
Peroxides and superoxides
9.7 Sulphides
9.8 Oxosalts – Carbonates, Bicarbonates, Nitrates, Nitrites and Sulphates
9.9 Halides and Polyhalides
9.10 Hydrides
9.11 Solubility and Hydration
9.12 Solutions of Metals in Liquid Ammonia
9.13 Compounds with Carbon
9.14 Complexes, Crowns and Crypts
9.15 Biological Importance
9.16 Differences between Lithium and the Other Group 1 Elements
9.17 Preparation of Sodium Hydroxide
9.18 Electrolytic Processes
Diaphragm cell
Mercury cathode cell
9.19 Preparation of Sodium Carbonate
9.20 The Solvay (or Ammonia – Soda) Process
Group 2 – The Alkaline Earth Elements
9.21 General Properties
Electronic structure
Size of atoms and ions
Ionization energy
Electronegativity
Hydration energies
Solubility and lattice energy
Solutions of the metals in liquid ammonia
9.22 Anomalous Behaviour of Beryllium
9.23 Chemical Properties
Reaction with water
9.24 Hydroxides
9.25 Hardness of Water
9.26 Reaction with Acids and Bases
9.27 Oxides and Peroxides
9.28 Sulphates
9.29 Nitrates
9.30 Hydrides
9.31 Halides
9.32 Nitrides
9.33 Carbides
9.34 Complexes
9.35 Biological Role of Mg2+ and Ca2+
9.36 Differences between Beryllium and the Other Group 2 Elements
Single Correct Choice Type Questions
Multiple Correct Choice Type Questions
Comprehension Type Questions
Assertion–Reasoning Type Questions
Integer Answer Type Questions
Matrix–Match Type Questions
Answers
10. The p-Block Elements and their Compounds
Part 1: The Group 13 Elements
10.1 Oxidation States and Types of Bonds
The (+III) oxidation state
The (+I) oxidation state – the ‘inert pair effect’
10.2 General Properties
Melting points, boiling points and structures i
Size of atoms and ions
Electropositive character
Ionization energy
10.3 Preparation of Boron
10.4 Reactions of Boron
10.5 Reactions of the Other Elements
Reaction with water and air
Reaction with acids and alkalis
Reaction with dioxygen
Reaction with the halogens and sulphate
Alums
Cement
10.6 Compounds of Boron and Oxygen
Boron sesquioxide and the borates
Acidic properties of H3BO3 or B(OH)3
Structures of borates
Borax
Sodium peroxoborate
Qualitative analysis of boron compounds
Fluoboric acid
10.7 The Other Group 13 Oxides
Preparation of Al2O3
Amphoteric behaviour – aluminates
10.8 Tetrahydridoborates (Borohydrides)
10.9 Halides
Trihalides
Dihalides
10.10 Complexes
10.11 Differences Between Boron and the Other Elements (Anomalous Behaviour of Boron)
10.12 Boron Hydrides
Compounds known
Preparation
10.13 Reactions of the Boranes
Hydroboration
Reaction with ammonia
Some other reactions of boranes
10.14 Structures of the Boranes
10.15 Organometallic Compounds
Single Correct Choice Type Questions
Multiple Correct Choice Type Questions
Comprehension Type Questions
Assertion–Reasoning Type Questions
Integer Answer Type Questions
Matrix–Match Type Questions
Answers
Part 2: The Group 14 Elements
10.16 Structure and Allotropy of the Elements
10.17 Differences Between Carbon, Silicon and the Remaining
Elements
10.18 Physical Properties
Covalent radii
Ionization energy
Melting points
Metallic and non-metallic character
Four-covalent compounds
10.19 Chemical Reactivity
Inert pair effect
10.20 Carbides
Salt-like carbides
Interstitial carbides
Covalent carbides
10.21 Oxygen Compounds of Carbon
Carbon monoxide CO
Carbon dioxide CO2
Carbon suboxides
10.22 Carbonates
10.23 Sulphides of Carbon
10.24 Oxides of Silicon
10.25 Oxides of Tin and Lead
Oxides of Tin
Oxides of Lead
10.26 Silicates
Occurrence in the Earth’s crust
Soluble silicates
10.27 Classification of Silicates
Orthosilicates (neso-silicates)
Pyrosilicates (soro-silicates, disilicates)
Cyclic silicates
Chain silicates
Sheet silicates (phyllo-silicates)
Three-dimensional silicates
10.28 Glass
10.29 Organosilicon Compounds and the Silicones
Organosilicon compounds
Preparation of organosilicon compounds
Silicones
10.30 Hydrides of Silicon
10.31 Complexes
10.32 Internal p Bonding Using d Orbitals
10.33 Halides
Tetrahalides
Catenated halides
Dihalides
10.34 Organic Derivatives
Single Correct Choice Type Questions
Multiple Correct Choice Type Questions
Comprehension Type Questions.
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